A great move means that this is the only move in a position, that works. That means, that this is the only move that doesn't lose (if a position is drawish), and the only move that keeps your advantage (if a position is winning for you). You can also see that in self-analysis, that that move is the only one. Although, sometimes it happens, that the great move is not the only one that works
Why is this a great move?
For example, you're in check, and one move to evade the check leads to a forced checkmate in x moves, another one leads to losing of material, and only one keeps the position drawish. That is a great move
I'm reviewing Hikaru vs Levy here, and at move 12. Bf4, the engine considers this a great move, why? I've followed the moves the engine provides to demonstrate this and arrive at a position that doesn't feel like it is massively in white's favour (at least not simply because the bishop is there).
Can someone explain in simple chess-principle terms why this move is so strong?